Tetrahedron

Conformational analysis—III: The reactions of the cyclooctenes with halogen, and the dipole moments of thecis-andtrans-1, 2-dichlorocyclooctanes

NL Allinger, LA Tushaus

文献索引：Allinger,N.L.; Tushaus,L.A. Tetrahedron, 1967 , vol. 23, p. 2051 - 2059

全文：HTML全文

被引用次数: 9

摘要

The addition of chlorine tocis-cyclooctene yields thetrans-dichloride, which has a dipole moment of 3· 1D, that is slightly solvent dependent. The correspondingcis-dichloride was not obtained by the chlorination of thetrans-olefin, but was synthesized indirectly, and found to have a dipole moment of 2· 3D, which is also solvent dependent. The addition of halogen totrans-cyclooctene was shown to yield a complex mixture of products, the major one ...