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Hydrogenation of oriented monolayers of. omega.-unsaturated fatty acids supported on platinum

MA Richard, J Deutch…

文献索引:Richard,M.A. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 6613 - 6625

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被引用次数: 25

摘要

Abstract: Oriented monolayers of an w-unsaturated fatty acid (1 7-octadecenoic acid, C 18: 1 17) have been prepared at the air-water interface and transferred to the surface of clean platinum foils. When the platinum-supported monolayer is exposed to dihydrogen, the olefinic group of the acid is hydrogenated. The rate of this reduction can be varied over a range of IO4 by changing the pH and metal ion concentration of the aqueous subphase on ...