Reduction of tungsten (VI) and molybdenum (V) by allyltrimethylsilane and cyclopentene. Simple high yield syntheses of MoCl 4 (OEt 2) 2, MoCl 4 (dme), WCl 4 (thf) 2, …
Convenient high yield methods to prepare MoCl 4 (OEt 2 ) 2 , MoCl 4 (dme), WCl 4 (thf) 2 , WCl 4 (dme) and WOCl 3 (thf) 2 by reduction of MoCl 5 and WCl 6 with olefins such as allyltrimethylsilane or cyclopentene are presented. ... W. Levason, CA McAuliffe, FP McCullough Jr. ... Cookies are used by this site. To decline or learn more, visit our Cookies page.