Heterogeneous Dehydrocoupling of Amine–Borane Adducts by Skeletal Nickel Catalysts

…, R Suter, L Chabanne, GR Whittell, I Manners

文献索引：Robertson, Alasdair P. M.; Suter, Riccardo; Chabanne, Laurent; Whittell, George R.; Manners, Ian Inorganic Chemistry, 2011 , vol. 50, # 24 p. 12680 - 12691

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被引用次数: 37

摘要

The catalytic dehydrogenation of various amine− borane adducts using a heterogeneous, skeletal Ni metal catalyst at 20° C has been demonstrated. The cyclic oligomer [MeNH− BH2] 3 was obtained from the catalytic dehydrogenation of MeNH2· BH3, whereas high molecular weight poly (methylaminoborane) was accessible using stoichiometric amounts of catalyst. Skeletal Cu was also shown to catalyze dehydrogenation of amine− borane ...