Synlett

Concise Syntheses of (7Z, 11Z, 13E)-Hexadecatrienal and (8E, 18Z)-Tetradecadienal

Z Ma, X Yang, Y Zhang, X Huang, Y Tao

文献索引：Ma, Zengxiao; Yang, Xiaomei; Zhang, Yushun; Huang, Xiangzhong; Tao, Yunhai Synlett, 2012 , # 4 p. 581 - 584

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摘要

Abstract Concise and efficient syntheses of (7Z, 11Z, 13E)-hexadecatrienal, a sex- pheromone component of the citrus leaf miner, and (8E, 10Z)-tetradecadienal, the sex pheromone of the horse-chestnut leaf miner were described, starting from the commercially available acetylene and acrolein. The stereoselective formation of E, Z-conjugated double bond relied on cross-coupling between Grignard reagent and (E, Z)-bromodiene. The ...