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284. The kinetics and mechanisms of addition to olefinic substances. Part IV. Rearrangement accompanying addition of hypochlorous acid to 3-chloro-2- …

P Ballinger, PBD de la Mare

文献索引:Ballinger; de la Mare Journal of the Chemical Society, 1957 , p. 1481,1482

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被引用次数: 5

摘要

CARBONIUM ions,-$-$-, are generally considered to be intermediates in the addition of hypochlorous acid to unsaturated compounds, and stereochemical evidence exists to show that the entering electrophilic chlorine atom can interact, electrostatically or otherwise, with