284. The kinetics and mechanisms of addition to olefinic substances. Part IV. Rearrangement accompanying addition of hypochlorous acid to 3-chloro-2- …

P Ballinger, PBD de la Mare

Index: Ballinger; de la Mare Journal of the Chemical Society, 1957 , p. 1481,1482

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Citation Number: 5

Abstract

CARBONIUM ions,-$-$-, are generally considered to be intermediates in the addition of hypochlorous acid to unsaturated compounds, and stereochemical evidence exists to show that the entering electrophilic chlorine atom can interact, electrostatically or otherwise, with