Solvolysis of D-glucopyranosyl derivatives in mixtures of ethanol and 2, 2, 2-trifluoroethanol

ML Sinnott, WP Jencks

文献索引：Sinnott, Michael L.; Jencks, William P. Journal of the American Chemical Society, 1980 , vol. 102, # 6 p. 2026 - 2032

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被引用次数: 123

摘要

Abstract: The products of solvolysis of a-and 0-D-ghcopyranosyl fluorides, 2, 4-dinitrophenyl 0-D-glucopyranoside, and the trifluoromethanesulfonates of the/% D-glucopyranosyl 3- bromopyridinium and aD-glucopyranosyl 4-methylpyridinium ions in an equimolar mixture of ethanol and trifluoroethanol buffered with-2 equiv of 2.6-lutidine have been examined by GLC of their trimethylsilyl ethers. The initial products of the solvolyses of phenyl a-and 0-D ...