Facile one-pot synthesis of bromo homoallyl alcohols and 1, 3-keto acetates via allyltin intermediates

…, J Nokami, T Yano, Y Yoshinaga, J Otera

文献索引：Mandai, Tadakatsu; Nokami, Junzo; Yano, Toru; Yoshinaga, Yukari; Otera, Junzo Journal of Organic Chemistry, 1984 , vol. 49, # 1 p. 172 - 174

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被引用次数: 74

摘要

11. When the reactions were conducted under the same conditions as for reaction 1 (method A), there were unexpectedly obtained 1, 3-keto acetates 3 in addition to normal products 2 (entries 1, 3, 5, and 9). Furthermore, it was found that employment of carbonyl compounds in excess (method B) resulted in the exclusive formation of 3 except for 3-(pheny1thio) propionaldehyde and benz-aldehyde (entries 4 and 6). Facile conversion of 2 to 3 may be ...