Abstract: The second-order reaction rates were measured for the MCPBA epoxidation in CHQ, for a series of cyclic olefins including bridgehead olefins and tram-cycloalkenes. As expected, strained bridgehead alkenes and trans-cycloalkenes showed faster reaction rates than nonstrained cis-cycloalkenes. The MM-2 steric energies of alkenes, alkanes, and their corresponding epoxides were calculated to evaluate the strain energy released in each ...
![bicyclo[4.3.1]dec-6-ene结构式](https://image.chemsrc.com/caspic/172/61764-75-8.png)
