Journal of the American Chemical Society

Oxidation of amines by a 4a-hydroperoxyflavin

S Ball, TC Bruice

文献索引：Ball, Sheldon; Bruice, Thomas C. Journal of the American Chemical Society, 1980 , vol. 102, # 21 p. 6498 - 6503

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被引用次数: 113

摘要

Abstract: Kinetic and product studies have been carried out for the reaction of 12 tertiary amines, secondary amines, and secondary hydroxylamines with the 4a-hydroperoxide of p- ethyl-3-methyllumiflavin (4a-FlEt00H). All reactions were found to be first order in 4a-HEt00H and amine in t-BuOH solvent. Transfer from 1-BuOH to the aprotic solvent dioxane decreases the second-order rate constant by-threefold, but does not change the kinetic ...