Bulletin of the Chemical Society of Japan

Cyclopropanes from allylic halides. I. Synthesis of dimethyl 3-(2-methyl-1-propenyl)-2, 2-dimethylcyclopropane-1, 1-dicarboxylate and pyrocin as precursors of …

S Torii, H Tanaka, Y Nagai

文献索引：Torii,S. et al. Bulletin of the Chemical Society of Japan, 1977 , vol. 50, p. 2825 - 2826

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被引用次数: 21

摘要

Cyclopropanes from allylic halides. I. Synthesis of dimethyl 3-(2-methyl-1-propenyl)-2,2-dimethylcyclopropane -1,1-dicarboxylate and pyrocin as precursors of chrysanthemic acid. ... Dimethyl 3-(2-methyl- 1-propenyl)-2,2-dimethyl-cyclopropane-1,1-dicarboxylate and pyrocin as precursors of chrysanthemic acid were synthesized by the reaction of (2-halo-2-methylpropylidene)malonate with 2-methyl-1-propenylmagnesium bromide. ...