(η 3: η 1 allylcarbonyl) iron tricarbonyl complexes. I. Transformation of complexes from electrophilic gem-dimethylcyclopropenes into functionalized isoprenic diene- …
M Franck-Neumann, C Dietrich-Buchecker…
文献索引：Franck-Neumann, M.; Dietrich-Buchecker, C.; Khemiss, A. Tetrahedron Letters, 1981 , vol. 22, # 24 p. 2307 - 2310
Abstract Electrophilic gem-dimethyl cyclopropenes react with diiron enneacarbonyl to give (η 3: η 1 allylcarbonyl) iron tricarbonyl complexes. These complexes, bearing in this work electron withdrawing substituents, are shown to be rather labile thermally and photochemically, leading easiyl to isoprenic diene-iron tricarbonyl complexes.
