The Journal of Organic Chemistry

Transmetalation reactions of alkylzirconocenes: copper-catalyzed conjugate addition to enones

P Wipf, JH Smitrovich

文献索引：Wipf, Peter; Smitrovich, Jacqueline H. Journal of Organic Chemistry, 1991 , vol. 56, # 23 p. 6494 - 6496

全文：HTML全文

被引用次数: 67

摘要

Summary: Rapid hydrozirconation of alkenes by zirconocene hydrochloride, followed by addition of 1 equiv of enone and catalytic amounts of Cu (1) salts, led to the corresponding 1, Caddition products in moderate to high yields and provided the first protocol for in situ preparation of alkyl cuprates from alkenes.