The Substituent Effect. XI. Solvolysis of 5-, 6-, and 7-Substituted 1-(1-Naphthylethyl) Chlorides

Y Tsuno, M Sawada, T Fujii, Y Tairaka…

文献索引：Tsuno,Y. et al. Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 3356 - 3366

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被引用次数: 16

摘要

Fourteen 5-, 6-, and 7-substituted 1-(1-naphthylethyl) chlorides were prepared and the solvolysis rates were determined in 80%(v/v) aqueous acetone at 45° C. The effects of− R substituents at respective positions were treated on the basis of the equation, logk⁄ k 0= ρ i σ i+ ρ x+ σ x+= ρ (C ij σ i+ q rij+ σ π+). The position dependency of the inductive effect was given by C ij (= ρ i⁄ ρ i, 4α); C 3α= 1.37, C 4α= 1.00, C 5α= 0.75, C 6α= 0.57, and C 7α= ...