The Journal of Organic Chemistry

Synthesis of phenoxyamines

AJ Castellino, H Rapoport

文献索引：Castellino, Angelo J.; Rapoport, Henry Journal of Organic Chemistry, 1984 , vol. 49, p. 1348 - 1352

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被引用次数: 21

摘要

Treatment of phenols with 2, 4-dinitrophenoxyamine leads to the synthesis of phenoxyamines through an amine exchange reaction. Yields for this reaction are sensitive to the pK, of the phenol in a manner explainable in terms of a competing bimolecular decomposition reaction involving the 2, 4-dinitrophenoxyamine. By use of an appropriately substituted phenol, this phenomenon can be exploited to give high yields of ...