Reactions of chloroformates with silver fluoro salts

P Beak, RJ Trancik, DA Simpson

文献索引：Beak,P. et al. Journal of the American Chemical Society, 1969 , vol. 91, p. 5073 - 5080

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被引用次数: 14

摘要

Abstract: The reactions of cyclohexyl, n-propyl, 1-apocamphyl, and phenyl chloroformates with silver tetrafluoroborate and silver hexafluoroantimonate give products formally derived from carboxylium and carbonium ions. The presence of the base, tetramethylurea, is required in the first two cases to eliminate the possibility that the observed products arise from transient olefin. The hypothesis that the processes involved in product formation may ...