The Coupling Action of the Grignard Reagent. V. The Influence of the Halogen Atom of the Reagent

E Ellingboe, RC Fuson

文献索引：Ellingboe; Fuson Journal of the American Chemical Society, 1933 , vol. 55, p. 2960,2965

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被引用次数: 9

摘要

The coupling action of the Grignard reagent on halogen compounds involves the linking of the radicals of the reagent as well as those of the compound upon which the reagent reacts. It has been observed in a large number of cases and is especially pronounced in connection with compounds containing the aryl halomethyl grouping, ArCX. The surprising fact that aryl polyhalomethyl derivatives such as benzal chloride and benzotrichloride also undergo ...