Electrophilic Displacement Reactions. VIII. 1 Rates of Brominolysis of Substituted Benzeneboronic Acids. Correlation of Rates of Aromatic Electrophilic Displacement …
HG Kuivila, LE Benjamin
文献索引：Kuivila; Benjamin Journal of the American Chemical Society, 1955 , vol. 77, p. 4834,4837
I favor formation of I when electron withdrawing substituents are present in the benzene ring. Since this reaction involves an atom in the side chain it should be correlated by the Hammett equation as is true for the ionization constants of substituted benzeneboronic acids. 5 From eq. 2 the concentration of the intermediate will be given by eq. 3 since
