The Rearrangement of 1, 1-Dimethyl-1-p-nitrobenzylamine-2-acetimide

S Wawzonek, E Yeakey

文献索引：Wawzonek,S.; Yeakey,E. Journal of the American Chemical Society, 1960 , vol. 82, p. 5718 - 5721

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被引用次数: 54

摘要

Evidence for the structure of XVI was its hydrolysis to 1, l-dimethyl-lp-nitrobenzylhydrazo- nium chloride (XIII). An attempt to prepare 1, l-dimethyl-lp-nitrobenzylaminimide from 1, l- dimethyl-1-+ nitrobenzylhydrazonium chloride (XIII) by treatment of the latter with sodium methoxide in methanol gave dimethyl-p-nitrobenzylamine. Formaldehyde and ammonia were also formed in this reaction. This decomposition resembles that observed with ...