… of hydrocarbons with (tetraarylporphyrinato) iron (III) complexes and molecular oxygen. Comparison with microsomal cytochrome P-450 mediated oxygenation …

L Weber, R Hommel, J Behling, G Haufe…

文献索引：Weber; Hommel; Behling; Haufe; Hennig Journal of the American Chemical Society, 1994 , vol. 116, # 6 p. 2400 - 2408

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被引用次数: 96

摘要

Abstract: Photocatalytic oxygenation of various alkenes with dioxygen and (5, 10, 15, 20- tetraarylporphyrinato) iron (III) complexes yielded allylic oxygenation products and/or epoxides. The product composition was found to be influenced both by the nature of the used substrate and by the concentrations, as well as the axial ligands. Alkenes with strained carbon double bonds gave preferentially epoxides whereas mainly allylic oxygenation ...