… of hydrocarbons with (tetraarylporphyrinato) iron (III) complexes and molecular oxygen. Comparison with microsomal cytochrome P-450 mediated oxygenation …

L Weber, R Hommel, J Behling, G Haufe…

Index: Weber; Hommel; Behling; Haufe; Hennig Journal of the American Chemical Society, 1994 , vol. 116, # 6 p. 2400 - 2408

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Citation Number: 96

Abstract

Abstract: Photocatalytic oxygenation of various alkenes with dioxygen and (5, 10, 15, 20- tetraarylporphyrinato) iron (III) complexes yielded allylic oxygenation products and/or epoxides. The product composition was found to be influenced both by the nature of the used substrate and by the concentrations, as well as the axial ligands. Alkenes with strained carbon double bonds gave preferentially epoxides whereas mainly allylic oxygenation ...