Porous siloxane linked phenylacetylene nitrile silver salts from solid state dimerization and low polymerization

YH Kiang, GB Gardner, S Lee, Z Xu

文献索引：Kiang; Gardner, Geoffrey B.; Lee, Stephen; Xu, Zhengtao Journal of the American Chemical Society, 2000 , vol. 122, # 29 p. 6871 - 6883

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被引用次数: 48

摘要

Three 3-fold symmetric rigid backbone phenylacetylene nitrile molecules have been prepared to which one to six hydroxy side chains have been attached. These molecules were cocrystallized with silver (I) trifluoromethanesulfonate (triflate) to form microcrystalline porous solids. X-ray powder data show that all three crystal structures are isotypic to the crystal structures found in previous single crystal studies on related systems. Structural ...