Porous siloxane linked phenylacetylene nitrile silver salts from solid state dimerization and low polymerization

YH Kiang, GB Gardner, S Lee, Z Xu

Index: Kiang; Gardner, Geoffrey B.; Lee, Stephen; Xu, Zhengtao Journal of the American Chemical Society, 2000 , vol. 122, # 29 p. 6871 - 6883

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Citation Number: 48

Abstract

Three 3-fold symmetric rigid backbone phenylacetylene nitrile molecules have been prepared to which one to six hydroxy side chains have been attached. These molecules were cocrystallized with silver (I) trifluoromethanesulfonate (triflate) to form microcrystalline porous solids. X-ray powder data show that all three crystal structures are isotypic to the crystal structures found in previous single crystal studies on related systems. Structural ...