Tetrahedron

Reaction of α-halo organoindium reagents with carbonyl compounds and electron-deficient alkenes

S Araki, T Hirashita, K Shimizu, T Ikeda, Y Butsugan

文献索引：Araki, Shuki; Hirashita, Tsunehisa; Shimizu, Ken; Ikeda, Takahiro; Butsugan, Yasuo Tetrahedron, 1996 , vol. 52, # 8 p. 2803 - 2816

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被引用次数: 28

摘要

A variety of α-halo organoindium reagents were prepared in situ from the reaction of gem- dihalo compounds with indium metal, and their reactions with carbonyl compounds and electron-deficient alkenes were examined. The reactions of simple 1, 1-diiodoalkanes with indium metal gave no defined products but benzal iodide gave stilbene in a moderate yield. α-Halo organoindium reagents drived from α, α-dibromo carbonyl compounds gave ...