Postsynthetic modification of an imine-based microporous organic network

PA Kerneghan, SD Halperin…

文献索引：Kerneghan, Phillip A.; Halperin, Shira D.; Bryce, David L.; Maly, Kenneth E. Canadian Journal of Chemistry, 2011 , vol. 89, # 5 p. 577 - 582

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被引用次数: 11

摘要

Abstract A highly cross-linked microporous organic network with imine linkers was prepared by condensation of tetrakis (4-aminophenyl) methane with terephthaldehyde. Gas adsorption studies indicate that the material exhibits permanent microporosity, and guest exchange experiments demonstrate that small molecules can diffuse into the network. Postsynthetic modification of this microporous network was achieved by treatment with ...