Postsynthetic modification of an imine-based microporous organic network

PA Kerneghan, SD Halperin…

Index: Kerneghan, Phillip A.; Halperin, Shira D.; Bryce, David L.; Maly, Kenneth E. Canadian Journal of Chemistry, 2011 , vol. 89, # 5 p. 577 - 582

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Citation Number: 11

Abstract

Abstract A highly cross-linked microporous organic network with imine linkers was prepared by condensation of tetrakis (4-aminophenyl) methane with terephthaldehyde. Gas adsorption studies indicate that the material exhibits permanent microporosity, and guest exchange experiments demonstrate that small molecules can diffuse into the network. Postsynthetic modification of this microporous network was achieved by treatment with ...