… 1, 3-Diphenylcyclopenta [l] phenanthrene-2-one, 1, 2, 3-Triphenylcyclopenta [l] phenanthrene-2-ol, 1-Chloro-1, 2, 3-triphenylcyclopenta [l] phenanthrene, 1-Bromo-1, 2 …

…, D Edwards-Davis, LD Field, AF Masters…

文献索引：Dennis, Glen D.; Edwards-Davis, David; Field, Leslie D.; Masters, Anthony F.; Maschmeyer, Thomas; Ward, Antony J.; Buys, Irmi E.; Turner, Peter Australian Journal of Chemistry, 2006 , vol. 59, # 2 p. 135 - 146

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被引用次数: 6

摘要

Abstract The photochemical reaction of 1, 3-diphenylcyclopenta [l] phenanthrene-2-one 5 (phencyclone) with oxygen in acetone leads to the formation of 1, 2, 3-trihydro-1, 2, 3- triphenylcyclo-penta [l] phenanthrene 7 (9, 10-dibenzoylphenanthrene) along with a trace of the lactone 1, 4-diphenylcyclo-3-pyran [l] phenanthrene-2-one 8. An independent synthesis of 8 was achieved by the reaction of 5 with FeCl 3 in CHCl 3. The treatment of 5 with ...