Organic letters

Formation of Organomagnesium Compounds via EtMgBr-Mediated Radical Cyclization of Allyl β-Iodoacetals

A Inoue, H Shinokubo, K Oshima

文献索引：Inoue, Atsushi; Shinokubo, Hiroshi; Oshima, Koichiro Organic Letters, 2000 , vol. 2, # 5 p. 651 - 653

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被引用次数: 39

摘要

Since the Grignard reagent was discovered in 1900, it has been widely used for the construction of organic molecules. It is the most basic and indispensable tool for organic chemists. 1 Grignard reagents have some common reaction patterns: (1) nucleophilic addition or substitution, (2) proton abstraction as a base, (3) magnesium−halogen exchange reactions. 2 There have been reports of some radical reactions using Grignard reagents in the presence or absence of a ...