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The Journal of Organic Chemistry

A new method for generating trichlorotitanium (IV) ester homoenolates. Direct tin-titanium exchange

R Goswami

文献索引:Goswami, Ramanuj Journal of Organic Chemistry, 1985 , vol. 50, # 26 p. 5907 - 5909

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被引用次数: 22

摘要

Summary: Treatment of the P-tri-n-butylstannyl derivatives of esters with titanium tetrachloride in dichloromethane effects tin-titanium exchange to generate trichlorotitanium (1V) homoenolate derivatives of the esters, which may then be used in further reaction with