Copper??Catalyzed Synthesis of α??Thioaryl Carbonyl Compounds Through S S and C C Bond Cleavage

…, DL Priebbenow, L Wang, J Mottweiler…

文献索引：Zou, Liang-Hua; Priebbenow, Daniel L.; Wang, Long; Mottweiler, Jakob; Bolm, Carsten Advanced Synthesis and Catalysis, 2013 , vol. 355, # 13 p. 2558 - 2563

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被引用次数: 23

摘要

Abstract: A method to access α-thioaryl ketones and α-thioaryl esters employing copper acetate (hydrate) as catalyst and readily accessible diaryl disulfides and β-diketones (or β- keto esters) has been developed. Both alkyl-and aryl-substituted carbonyl compounds can be prepared. Keywords: α-arylthio esters; α-arylthio ketones; CÀ C bond cleavage; copper catalysis; diaryl disulfides α-Thioaryl carbonyl compounds are useful intermediates in ...