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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Tetrahedron

Synthesis of α-selenoalkyllithium compounds

…, W Dumont, M Clarembeau, G Bernard, E Badaoui

文献索引：Krief, A.; Dumont, W.; Clarembeau, M.; Bernard, G.; Badaoui, E. Tetrahedron, 1989 , vol. 45, # 7 p. 2005 - 2022

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被引用次数: 111

摘要

α-Phenylselenoalkyllithiums and α-methylselenoalkyllithiums have been prepared from the corresponding selenoacetals and alkyllithiums. Several features of this reaction are disclosed. For example, the reaction is more readily achieved on phenylselenoacetals than on methylseleno analogues. Those derived from hindered carbonyl compounds are less readily cleaved. s-BuLi/THF proved superior to n-BuLi in THF, itself better than n-BuLi in ...

苯硫酚钾结构式

~%

methylselanylbenzene结构式

methylselanylbenzene

phenylselanylmethylselanylbenzene结构式

phenylselanylme...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

methylselanylbenzene结构式

methylselanylbenzene

详细

溴代正癸烷结构式

溴代正癸烷

((methylselanyl)methyl)lithium结构式

((methylselanyl...

~2%

1-methylselanyldecane结构式

1-methylselanyl...

1-methylselanylundecane结构式

1-methylselanyl...

二碘甲烷结构式

potassium methanethiolate结构式

potassium metha...

~%

bis(methylselanyl)methane结构式

bis(methylselan...

溴代正癸烷结构式

溴代正癸烷

lithium,methanidylselanylbenzene结构式

lithium,methani...

~2%

decylselanylbenzene结构式

decylselanylbenzene

未登录结构式

苯甲醛结构式

1,1-bis(methylseleno)-2-methylcyclohexane结构式

1,1-bis(methyls...

~%

2-methylselanylbutane结构式

2-methylselanyl...

未登录结构式

苯甲醛结构式

2,2-bis(methylseleno)adamantane结构式

2,2-bis(methyls...

~%

2-methylselanylbutane结构式

2-methylselanyl...

未登录结构式

溴代正癸烷结构式

溴代正癸烷

((methylselanyl)methyl)lithium结构式

((methylselanyl...

~87%

1-methylselanyldecane结构式

1-methylselanyl...

1-methylselanylundecane结构式

1-methylselanyl...

未登录结构式

苯甲醛结构式

~%

butan-2-ylselanylbenzene结构式

butan-2-ylselan...

1,2-diphenyl-2-methylseleno-ethane-1-ol结构式

1,2-diphenyl-2-...

1,1-bis(phenylselenenyl)-2-methylcyclohexane结构式

1,1-bis(phenyls...

苯甲醛结构式

~%

butan-2-ylselanylbenzene结构式

butan-2-ylselan...

phenyl-[(1-phenylseleno-2-methyl)cyclohexyl]-methanol结构式

phenyl-[(1-phen...

苯硫酚钾结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

1,1-bis(phenylselenenyl)-4-tert-butylcyclohexane结构式

1,1-bis(phenyls...

~%

butylselanylbenzene结构式

butylselanylbenzene

trans-1-phenylselenenyl-4-tert-butylcyclohexane结构式

trans-1-phenyls...

1,1-bis(phenylselenenyl)-2-methylcyclohexane结构式

1,1-bis(phenyls...

~%

butylselanylbenzene结构式

butylselanylbenzene

未登录结构式

phenylselanylmethylselanylbenzene结构式

phenylselanylme...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

1-phenyl-2-(phenylselanyl)ethanol结构式

1-phenyl-2-(phe...

1-phenylselanylethylselanylbenzene结构式

1-phenylselanyl...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

1-phenyl-2-phenylselanyl-propan-1-ol结构式

1-phenyl-2-phen...

1-phenylselanylheptylselanylbenzene结构式

1-phenylselanyl...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

未登录结构式

2,2-bis (phenylseleno)propane结构式

2,2-bis (phenyl...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

2-Methyl-1-phenyl-2-phenylseleno-1-propanol结构式

2-Methyl-1-phen...

(1-phenylselanylcyclopentyl)selanylbenzene结构式

(1-phenylselany...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

phenyl-[(1-phenylseleno)cyclopentyl]-methanol结构式

phenyl-[(1-phen...

1,1-bis(phenylselenenyl)cyclohexane结构式

1,1-bis(phenyls...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

phenyl-[(1-phenylseleno)cyclohexyl]-methanol结构式

phenyl-[(1-phen...

1-phenyl-1,1-bis(phenylseleno)ethane结构式

1-phenyl-1,1-bi...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

1,2-diphenyl-2-methylseleno-propane-1-ol结构式

1,2-diphenyl-2-...

1,1-bis(phenylselenenyl)-4-tert-butylcyclohexane结构式

1,1-bis(phenyls...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

未登录结构式

7-phenylselanyltridecan-7-ylselanylbenzene结构式

7-phenylselanyl...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

未登录结构式

1,1-(bisphenylseleno)cyclopropane结构式

1,1-(bisphenyls...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

phenyl-[(1-phenylseleno)cyclopropyl]-methanol结构式

phenyl-[(1-phen...

bis(phenylselanyl)methylbenzene结构式

bis(phenylselan...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

未登录结构式

1-phenylselanylpropylselanylbenzene结构式

1-phenylselanyl...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

1-phenyl-2-phenylselenobutane-1-ol结构式

1-phenyl-2-phen...

1,1-bis(phenylseleno)cyclobutane结构式

1,1-bis(phenyls...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

phenyl-[(1-phenylseleno)cyclobutyl]-methanol结构式

phenyl-[(1-phen...

苯甲醛结构式

1,1-bis(phenylseleno)-2,2-dimethyl-propane结构式

1,1-bis(phenyls...

~%

butylselanylbenzene结构式

butylselanylbenzene

1-phenyl-2-phenylseleno-3,3-dimethyl-butane-1-ol结构式

1-phenyl-2-phen...

苯甲醛结构式

2,2-bis(phenylseleno)-3,3-dimethyl-butane结构式

2,2-bis(phenyls...

~%

butylselanylbenzene结构式

butylselanylbenzene

1-phenyl-2-phenylseleno-2,3,3-trimethyl-butane-1-ol结构式

1-phenyl-2-phen...

苯甲醛结构式

2,2-bis(phenylselenyl) octane结构式

2,2-bis(phenyls...

~%

butylselanylbenzene结构式

butylselanylbenzene

未登录结构式

phenylselanylmethylselanylbenzene结构式

phenylselanylme...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

methylselanylbenzene结构式

methylselanylbenzene

详细

1-phenylselanylheptylselanylbenzene结构式

1-phenylselanyl...

苯甲醛结构式

~%

butylselanylbenzene结构式

butylselanylbenzene

1-phenyl-2,2-bis(phenylselanyl)octan-1-ol结构式

1-phenyl-2,2-bi...

详细

二碘甲烷结构式

苯硫酚钾结构式

~%

phenylselanylmethylselanylbenzene结构式

phenylselanylme...

A novel and highly efficient synthetic route to unsymmetrica...

[Cohen, Richard J.; Fox, Daniel L.; Salvatore, Ralph Nicholas Journal of Organic Chemistry, 2004 , vol. 69, # 12 p. 4265 - 4268]

Nucleophilic cleavage of lactones and esters with zinc selen...

[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]

Nucleophilic cleavage of lactones and esters with zinc selen...

[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]

Nucleophilic cleavage of lactones and esters with zinc selen...

[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]

Nucleophilic cleavage of lactones and esters with zinc selen...

[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]