The Rearrangement of Some Disubstituted Cyclic Ketones: An Unusual Dienone—Phenol Rearrangement1

EN Marvell, AO Geiszler

文献索引：Marvell; Geiszler Journal of the American Chemical Society, 1952 , vol. 74, p. 1259,1262

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被引用次数: 11

摘要

The preparation and rearrangement of two l-oxo-2, 2-dialkyl-l, 2-dihydronaphthalenes are described. Evidence for the structure of these compounds is given and the products of the rearrangements are identified as 3, 4-dialkyl-l-naphthol derivatives. This rearrangement is most unusual since the same products are obtained upon rearrangement of 1-oxo-4.4- dialkyl-l, 2-dihydronaphthalenes under identical conditions.