Organophosphorus??Catalysed Staudinger Reduction

…, JJ Bruins, FPJT Rutjes, FL van Delft

文献索引：Van Kalkeren, Henri A.; Bruins, Jorick J.; Rutjes, Floris P. J. T.; Van Delft, Floris L. Advanced Synthesis and Catalysis, 2012 , vol. 354, # 8 p. 1417 - 1421

全文：HTML全文

被引用次数: 38

摘要

Abstract The first Staudinger reduction that is catalytic in phosphine has been developed, showing excellent yields and functional group selectivity. To this end we utilised dibenzophosphole catalysts and mild in situ reduction of the intermediate iminophosphoranes. We could avoid the necessity of water during the reduction, obtained no phosphine oxides as waste and thus enabled facile purification of the product. A range ...