Solvent effects on displacement of fluoride ion from isopropyl methylphosphonofluoridate

GT Davis, MM Demek, JR Sowa…

文献索引：Davis,G.T. et al. Journal of the American Chemical Society, 1971 , vol. 93, p. 4093 - 4103

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被引用次数: 4

摘要

Abstract: Studies have been made on the rate of displacement of fluoride ion from isopropyl methylphosphonofluoridate (I) by oxygen nucleophiles in dipolar aprotic solvents and methanol.(Comparable data in aqueous solution are available.) In dipolar aprotic solvents the reaction between a nucleophile which forms a stable phosphonylated product and I can be written as simple equilibrium: The equilibrium lies far to the left if the anion is m-or p- ...