Photoreactions of α-sulfonyloxyketones

JL Charlton, HK Lai, GN Lypka

文献索引：Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462

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被引用次数: 11

摘要

Earlier work on the photochemistry of α-sulfonyloxyketones uncovered their propensity to form the corresponding α-keto carbonium ions on photolysis. Typical reactions such as intramolecular cyclizations, carbonium ion rearrangements, and solvent trapping were found. This paper describes an attempt to extend this reaction to a general synthetic technique for polyene cyclizations. During the course of this work two other major reaction ...

~67%

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~61%

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~38%

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~86%

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