Preparation of unsaturated nitriles

M Procházka, M Široký

文献索引：Prochazka, Milos; Siroky, Miroslav Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 6 p. 1765 - 1773

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被引用次数: 34

摘要

Abstract The yield and the rate of formation of nitriles X-CH= CH-CN and 3-and 4-substituted nitriles XC 6 H 5 CN (X= CH 3; OR; SR; COOCH 3) were investigated in the reaction of vinyl and aryl bromides with CN (-), under catalysis with Pd 0 and macrocyclic polyethers, and in the reaction with CuCN in dipolar aprotic solvents. Individual procedures were compared from the point of view of the possibility of a preparative utilization.