Chemical Communications 2012-01-30

Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.

Ben W Glasspoole, Kazem Ghozati, Jonathon W Moir, Cathleen M Crudden

文献索引：Chem. Commun. (Camb.) 9th ed., 48 , 1230-1232, (2012)

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摘要

Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.