Chemical Communications 2012-01-30

Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.

Ben W Glasspoole, Kazem Ghozati, Jonathon W Moir, Cathleen M Crudden

Index: Chem. Commun. (Camb.) 9th ed., 48 , 1230-1232, (2012)

Full Text: HTML

Abstract

Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.