Synthesis

Amination of (η3-Allyl) dicarbonylnitrosyliron Complexes: A Route to γ-Amino-α, β-unsaturated Carboxylic Acid Derivatives

S Nakanishi, K Okamoto, H Yamaguchi, T Takata

文献索引：Nakanishi, Saburo; Okamoto, Kenji; Yamaguchi, Hiroshi; Takata, Toshikazu Synthesis, 1998 , # 12 p. 1735 - 1741

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摘要

Abstract: Amines reacted regioselectively with (η3-allyl) dicarbonylnitrosyliron complexes having ester group on the allyl ligand to give γ-amino-α, β-unsaturated esters in high yields. A remarkable effect of the substituents attached to the allyl ligand was observed on the reaction rate and regioselectivity of the amination. The methoxycarbonyl group significantly accelerates the reaction rate and enhances the regioselectivity of the reaction. The phenyl ...