Canadian Journal of Chemistry

Formation and reactivity of 1, 3-benzodioxol-2-yl, 1, 3-benzodioxan-2-yl, and related radicals. A search for an aromatic analog of the radical acetoxy rearrangement ( …

F Shahidi, TT Tidwell

文献索引：Shahidi, Fereidoon; Tidwell, Thomas T. Canadian Journal of Chemistry, 1982 , vol. 60, p. 1092 - 1097

全文：HTML全文

被引用次数: 8

摘要

Reaction of the 1, 3-dioxole, 9, the 1, 3-dioxan, 18, and the 1, 3-dioxepin, 29, with tert-butoxy radicals gave evidence in each case for formation of the corresponding 1, 1-dioxyethyl radicals. No conclusive evidence for formation of any of these radicals by cyclization of acetoxyaryl radicals could be obtained. Several of the 1, 1-dioxyethyl radicals reacted by rearrangement.