Catalytic Activation of Diazo Compounds Using Electron??Rich, Defined Iron Complexes for Carbene??Transfer Reactions

MS Holzwarth, I Alt, B Plietker

文献索引：Holzwarth, Michael S.; Alt, Isabel; Plietker, Bernd Angewandte Chemie - International Edition, 2012 , vol. 51, # 22 p. 5351 - 5354

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被引用次数: 22

摘要

The activation of diazo compounds by nitrogen extrusion in the presence of transition-metal complexes is a convenient method for the transfer of a carbene to an organic substrate in, for example,[2+ 1] cycloadditions with olefins [1] or carbonyl compound [2] to give three- membered-ring compounds, or in reactions with electron-rich heteroatoms like sulfur,[3] phosphorus,[4] and nitrogen [5] to generate ylides.[6] In general, these types of reactions ...