Reactions of bis (trimethylsilyl) isocyanamine and its isomers with chlorotriphenylphosphonium chloride: evidence for a transient …

G Zinner, G Beck, WP Fehlhammer, N Wiberg

文献索引：Zinner, Gerhard; Beck, Gerhard; Fehlhammer, Wolf P.; Wiberg, Nils Journal of Organometallic Chemistry, 1989 , vol. 368, p. 23 - 30

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被引用次数: 7

摘要

Abstract Triphenylphosphine dichloride reacts with (Me 3 Si) 2 C NN, Me 3 SiN C NSiMe 3, and metal-coordinated CN N (SiMe 3) 2 to give the iminophosphoranes CN NPPh 3, NC NPPh 3, and W (CO) 5 CN NPPh 3, respectively, and with free bis (trimethylsilyl) isocyanamine to give a dicationic species containing a tetrazole ring with triphenylphosphonio and bis (triphenylphosphonio) methylide substituents. This latter ...