Chemistry–A European Journal

Iron (III) Corroles and Porphyrins as Superior Catalysts for the Reactions of Diazoacetates with Nitrogen??or Sulfur??Containing Nucleophilic Substrates: Synthetic Uses …

I Aviv, Z Gross

文献索引：Aviv, Iris; Gross, Zeev Chemistry - A European Journal, 2008 , vol. 14, # 13 p. 3995 - 4005

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被引用次数: 68

摘要

Abstract A thorough mechanistic investigation has been performed on the reactions of primary and secondary amines with diazoacetates, which proceed uniquely quickly and efficiently when catalyzed by iron (III) corroles and porphyrins. Two major differences in relation to other metal-based catalysts are that the iron complexes are not poisoned by excess amine and that metal–carbene intermediates are apparently not involved in the ...