Aggregative activation in heterocyclic chemistry. Part 5.† Lithiation of pyridine and quinoline with the complex base BuLi· Me 2 N (CH 2) 2 OLi (BuLi· LiDMAE)

P Gros, Y Fort, P Caubère

文献索引：Gros, Philippe; Fort, Yves; Caubere, Paul Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 24 p. 3597 - 3600

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被引用次数: 70

摘要

J. Chem. Soc., Perkin Trans. 1, 1997 3597 ... Aggregative activation in heterocyclic chemistry. Part 5.† Lithiation of ... Philippe Gros, Yves Fort and Paul Caubère * ... Laboratoire de Chimie Organique I, Unité Associée au CNRS no 457, Faculté des Sciences, Université Henri Poincaré Nancy-I, BP 239, F-54506 Vandoeuvre-les-Nancy Cédex, France ... It is shown that the complex base BuLi LiDMAE reacts with pyridine to give metallated species which, ...

~56%

~40%

~45%

~43%

~36%

~41%

~73%

~30%

~25%

~1%

~1%

~31%

~13%

~3%

~65%

~82%

~80%

Simple syntheses of aryl alkyl thioethers and of aromatic th...

[Testaferri, L.; Tiecco, M.; Tingoli, M.; Chianelli, D.; Montanucci, M. Synthesis, 1983 , # 9 p. 751 - 755]