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Organic Letters 2000-10-01

Facile, completely regioselective 1,4-hydrogenations of C(60)-diaryltetrazine monoadducts

Miller, Tetreau

文献索引:Org. Lett. 2(20) , 3091-4, (2000)

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摘要

Thermal Diels-Alder reactions between C(60) and electron-deficient 3, 6-diaryl-1,2,4,5-tetrazines yield monoadducts possessing a diaryldihydropyridazine function nested atop the fullerene. The diaryldihydropyridazine functions direct a completely regioselective 1,4-hydrogenation, resulting in a racemic mixture of bifunctional bisadduct (+/-)-3.

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