Organic Letters 2000-10-01

Facile, completely regioselective 1,4-hydrogenations of C(60)-diaryltetrazine monoadducts

Miller, Tetreau

Index: Org. Lett. 2(20) , 3091-4, (2000)

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Abstract

Thermal Diels-Alder reactions between C(60) and electron-deficient 3, 6-diaryl-1,2,4,5-tetrazines yield monoadducts possessing a diaryldihydropyridazine function nested atop the fullerene. The diaryldihydropyridazine functions direct a completely regioselective 1,4-hydrogenation, resulting in a racemic mixture of bifunctional bisadduct (+/-)-3.

Structure	Name/CAS No.	Molecular Formula	Articles
	1,2,4,5-Tetrazine,3,6-diphenyl- CAS:6830-78-0	C₁₄H₁₀N₄

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Reaction of 3, 6-diphenyl-1, 2, 4, 5-tetrazine with cis, cis...
[Tetrahedron 35(2) , 277-85, (1979)]

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[Chem. Heterocycl. Comp. 34(1) , 111-114, (1998)]

Facile, completely regioselective 1,4-hydrogenations of C(60)-diaryltetrazine monoadducts

Abstract

Related Compounds