The Journal of Organic Chemistry

Cationic carbon to nitrogen rearrangements in the reactions of N-(sulfonyloxy) amines with aldehydes

RV Hoffman, JM Salvador

文献索引：Hoffman, Robert V.; Salvador, James M. Journal of Organic Chemistry, 1992 , vol. 57, # 16 p. 4487 - 4490

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被引用次数: 9

摘要

A series of aromatic and aliphatic aldehydes was reacted with N-(@-nitrobenzenesulfony1) oxy) methylamine in chloroform. Products resulting from both carbon migration and hydride migration to nitrogen were isolated. The ratios of carbon to hydride migration products were used to clarify the reaction mechanism. The results support a two-step process in which cationic carbon to nitrogen rearrangement is rate determining.