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Probing Electron Transfer in the Manganese–Oxide‐Forming MnxEFG Protein Complex using Fourier‐Transformed AC Voltammetry: Understanding the Oxidative Priming Effect

10.1002/celc.201800219

2018-02-21

The Cover Feature illustrates the manganese oxidizing MnxEFG protein complex immobilized on an electrode surface and probed by Fourier‐transformed alternating current voltammetry. This analysis enables the detection of electron transfer of the copper co‐facto...

Enhanced Stability of Lithium Metal Anode by using a 3D Porous Nickel Substrate

10.1002/celc.201800216

2018-02-21

The Cover Feature illustrates a 3D Ni framework with Li embedded inside (top figure), which enables the fast transfer of electrons and Li ions through the whole electrode and full utilization of the Li electrode. However, a 2D Li structure (bottom figure) lea...

Electrochemical Investigation of the Kinetics of Chloride Substitution upon Reduction of [Ru(porphyrin)(NO)Cl] Complexes in Tetrahydrofuran

10.1002/celc.201800218

2018-02-21

The Front Cover shows cartoons of species formed during cyclic voltammetry (CV) analysis of [Ru(porphyrin)(NO)Cl] in tetrahydrofuran. The initial redox‐induced reversible solvent‐for‐chloride metathesis shown in the reaction at the top occurs at diffusion‐lim...

Synergistic Hematite–Fullerene Electron-Extracting Layers for Improved Efficiency and Stability in Perovskite Solar Cells

10.1002/celc.201800215

2018-02-21

The Front Cover illustrates that inorganic hematite can synergistically work together with organic fullerene as an efficient electron-extracting material in heterojunction perovskite solar cells. More information can be found in the Communication by Q. Hou et...

Reaching Highly Stable Specific Capacity with Integrated 0.6Li2MnO3 : 0.4LiNi0.6Co0.2Mn0.2O2 Cathode Materials

10.1002/celc.201701193

2018-02-20

The work described herein was performed to find guidelines for the optimal selection of high‐specific‐capacity cathode materials for Li‐ion batteries. In this study, we compared the electrochemical behavior of three cathode materials working over wide potenti...

Investigating the Role of Oxygen Vacancies and Lattice Strain Defects on the Enhanced Photoelectrochemical Property of Alkali Metal (Li, Na, and K) Doped ZnO Nanorod Photoanodes

10.1002/celc.201800097

2018-02-20

This work demonstrates the significance of defect engineering in tuning the visible‐light‐driven photoelectrochemical property of alkali metal (Li, Na, and K) doped ZnO nanorods. The large concentration of oxygen vacancies introduced into the sub‐bandgap, bec...

Understanding the Cyclic (In)stability and the Effects of Presence of a Stable Conducting Network on the Electrochemical Performances of Na2Ti3O7

10.1002/celc.201701276

2018-02-20

Despite being a promising anode material for the Na‐ion battery system, Na‐titanate (viz., Na2Ti3O7) lacks in terms of cyclic stability; the cause(s) for which are under debate. Against this backdrop, through electrochemical measurements and in situ synchrotr...

Diazonium Grafting Control through a Redox Cross‐Reaction: Elucidation of the Mechanism Involved when using 2,2‐Diphenylpicrylhydrazyl as an Inhibitor

10.1002/celc.201701331

2018-02-19

Investigation into the mechanism involved in the control of layer growth through the reduction of diazonium salts by using 2,2‐diphenylpicrylhydrazyl (DPPH). This approach, previously assumed to be based on the radical capture of highly reactive aryl intermed...

Synergistic Hematite–Fullerene Electron-Extracting Layers for Improved Efficiency and Stability in Perovskite Solar Cells

10.1002/celc.201800214

2018-02-19

Abstract The front cover artwork is provided by Prof. Zhanhu Guo from the University of Tennessee, Knoxville (USA) and Profs. Ning Wang and Qiang Luo from the University of Electronic Science and Technology of China. The image shows that inorganic hematite ca...

Conserved Histidine Adjacent to the Proximal Cluster Tunes the Anaerobic Reductive Activation of Escherichia coli Membrane‐Bound [NiFe] Hydrogenase‐1

10.1002/celc.201800047

2018-02-16

[NiFe] hydrogenases are electrocatalysts that oxidize H2 at a rapid rate without the need for precious metals. All membrane‐bound [NiFe] hydrogenases (MBH) possess a histidine residue that points to the electron‐transfer iron sulfur cluster closest (“proximal...