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The chemistry of PET imaging with zirconium-89
10.1039/C7CS00014F 2018-03-20 This Tutorial Review aims to provide an overview of the use of zirconium-89 complexes in biomedical imaging. Over the past decade there have been many new papers in this field, ranging from chemistry through to preclinical and clinical applications. Here we a... |
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Advances in liquid metals for biomedical applications
10.1039/C7CS00309A 2018-03-20 To date, liquid metals have been widely applied in many fields such as electronics, mechanical engineering and energy. In the last decade, with a better understanding of the physicochemical properties such as low viscosity, good fluidity, high thermal/electri... |
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Photochemistry and photophysics of MOFs: steps towards MOF-based sensing enhancements
10.1039/C7CS00861A 2018-03-16 In this review, we highlight how recent advances achieved in the fields of photochemistry and photophysics of metal–organic frameworks (MOFs) could be applied towards the engineering of next generation MOF-based sensing devices. In addition to high surface ar... |
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Reactions of secondary propargylamines with heteroallenes for the synthesis of diverse heterocycles
10.1039/C7CS00065K 2018-03-16 This focused review aims to summarize recent developments in the processes involving additions of secondary propargylamines to various heteroallenes and subsequent transition metal-catalyzed or electrophile-mediated cyclizations. The utility of this convenien... |
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Thermodynamic and kinetic hydricities of metal-free hydrides
10.1039/C7CS00171A 2018-03-15 Metal-free hydrides are of increasing research interest due to their roles in recent scientific advances in catalysis, such as hydrogen activation with frustrated Lewis pairs and electrocatalytic CO2 reduction with pyridinium and other aromatic cations. The s... |
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Imaging the chemical activity of single nanoparticles with optical microscopy
10.1039/C7CS00451F 2018-03-15 Nanomaterials exhibit structural and functional heterogeneity among individual nanoparticles, thus requiring a capability to study single nanoparticles. While electron microscopes often provide static images of their chemical composition, morphology and struc... |
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A guide to integrating immunohistochemistry and chemical imaging
10.1039/C7CS00610A 2018-03-15 Chemical imaging provides new insight into the fundamental atomic, molecular, and biochemical composition of tissue and how they are interrelated in normal physiology. Visualising and quantifying products of pathogenic reactions long before structural changes... |
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Protein delivery into cells using inorganic nanoparticle–protein supramolecular assemblies
10.1039/C8CS00008E 2018-03-14 The delivery of proteins into cells is a potential game changer for a wide array of therapeutic purposes, including cancer therapy, immunomodulation and treatment of inherited diseases. In this review, we present recently developed nanoassemblies for protein ... |
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Sensing and capture of toxic and hazardous gases and vapors by metal–organic frameworks
10.1039/C7CS00885F 2018-03-13 Toxic and hazardous chemical species are ubiquitous, predominantly emitted by anthropogenic activities, and pose serious risks to human health and the environment. Thus, the sensing and subsequent capture of these chemicals, especially in the gas or vapor pha... |
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Chemical synthesis of two-dimensional atomic crystals, heterostructures and superlattices
10.1039/C7CS00887B 2018-03-12 Two-dimensional atomic crystals (2DACs) have attracted intense recent interest. With a nearly perfect crystalline structure and dangling-bond free surface, these atomically thin materials have emerged as a new material platform for fundamental materials scien... |